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University of Wisconsin Stevens Point

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Third atmosphere - free oxygen

About 2 billion years ago, free oxygen began to accumulate in our atmosphere. Organisms with traits of both blue-green algae and bacteria released oxygen as a waste product of their metabolism. In the next 1.5 billion years, atmospheric oxygen levels increased, carbon dioxide levels decreased, and an ozone layer formed.

Without ozone protection, scientists think that the sun’s radiation would have prevented any animals from living on land.

Visitors may touch these specimens.

How do scientists know free oxygen increased in our atmosphere?

Beginning about 3.5 bya, banded iron ore deposits began to form underwater. Reduced iron (without oxygen) and silica washed into the ocean, combined with oxygen produced by algae, and settled together in banded layers. About 2 bya oceans saturated with oxygen released free oxygen to the atmosphere. Reduced iron no longer existed on the surface; banded iron ore deposits ceased to form.

Specimens on exhibit  
Banded iron ore Lake Superior, west of Marquette, Michigan. Note the layers of red rust.
Stromatolite Formed when silt and/or sand settled on mats of blue-green algae/bacteria, stromatolites still form in hot springs, lakes, and seas. Found in Wisconsin and formed 450 million years ago, this sample appears similar to stromatolites formed billions of years ago that helped form banded iron ore.

 

Is there any evidence to show that atmospheric oxygen levels increased?

Yes. About the same time banded iron ore stopped forming underwater, "rusty" red beds of sedimentary rock began to form on land. Free atmospheric oxygen began to oxidize iron on Earth’s surface.

Specimens on exhibit  
Sandstone and shale (reddish color) Both samples formed in the presence of free atmospheric oxygen; they contain reddish iron oxide.

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